Mercury batteries used to be good DC voltage standards.  OSHA made certain that resource for a voltage reference became unavailable some decades ago.  
They were still considered a reasonably good standard when I was in college some 55 year ago.
Dave - WØLEV
Hi Tom,Fully agree that petrology calibration costs are prohibitive for the average punter. I use what's called a 'transfer' method to validate voltage measurements.This involves something as simple as say a lithium button battery, where you physically take that battery to a place that has say a 7.5 digit multimeter, log the reading, then compare it to your own multimeter..David Burger VK2CZ
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Dave - WØLEV
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